Stoichiometric oxidations of -bonds: Radical and possible non-radical pathways

نویسندگان

  • James M. Mayer
  • Elizabeth A. Mader
  • Justine P. Roth
  • Jasmine R. Bryant
  • Takashi Matsuo
  • Ahmad Dehestani
  • Brian C. Bales
  • Eric J. Watson
  • Takao Osako
  • Karine Valliant-Saunders
  • Wai Han Lam
  • David A. Hrovat
  • Ernest R. Davidson
چکیده

Many transition metal complexes accomplish or catalyze the oxidation of C H, O H, and other -bonds. Under aerobic conditions, metal complexes typically modulate an autoxidation radical chain. In anaerobic reactions, a metal complex can be the reactive species that attacks t c a r h s d ©

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تاریخ انتشار 2006